Research Interest:
Synthesis and characterization of the structural and physical properties of (i) Novel relaxor-based piezo-/ferroelectric single crystals, (ii) Ferroelectrics for non-volatile random access memories (FeRAM), (iii) Crystalline oxides on Si & gate dielectrics, (iv) Magnetically ordered ferroelectric / ferroelastic materials, and (v) photovoltaic and optoelectronic materials.
Current Research Topics:
- Growth, by various techniques, of the innovative high strain piezoelectric single crystals belonging to the relaxor ferroelectric and ferroelectric solid solution systems: (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 [PMN-PT], (1-x)Pb(Zn1/3Nb2/3) O3-xPbTiO3 [PZN-PT], and (1-x)Pb(Sc1/2Nb1/2)O3-xPbTiO3 [PSN-PT], and some new solid solution systems.
- Crystal Growth of halide perovskites, including organic-inorganic halide perovskites and all-inorganic perovskites, APbX3 (A= CH3NH3, Cs, K, and X= I, Br, Cl), and studies of phase symmetries, domain structures, and physical properties.
- Synthesis of the above-mentioned materials in the forms of nanoparticles, dense ceramics and thin films by solid state reactions and chimie douce approaches.
- Preparation of magnetically ordered dielectric and ferroelectric crystals and thin films: REMnO3 (RE=Ho, Er, Tm, Yb Lu or Y) and MBO3 (M=Fe3+, V3+, Cr3+ and Ti3+); Investigation of their potential as gate dielectrics in Si technologies.
- Synthesis of ferroelectric layered perovskite SrBi2Ta2O9 [SBT] and related compounds in the forms of single crystals and ceramics; study of their anisotropic properties;
- Determination of nuclear and magnetic structures of the materials by (synchrotron) X-ray and neutron diffraction, with emphasis on the morphotropic phase boundary behavior and its effects on the properties.
- Thermoanalysis of the relaxor systems for establishment of the relevant phase diagrams.
- Characterization of the dielectric, piezoelectric, pyroelectric, ferroelectric and magnetoelectric properties.
- Investigation of the mesoscopic domain structures and their effects on the macroscopic electric and magnetic properties, and thereby the related device performance.
- Studies of the phase transitions as a function of temperature and the phase transitions induced by electric field, mechanical stress and magnetic field.
- Studies of the dielectric relaxation and critical behavior in relaxor materials by impedance spectroscopy; modeling of the microscopic origin and mechanisms of relaxor ferroelectricity; establishment of the microstructure and property relationships.
- Development of ferroic materials for applications of in advance technologies, such as (i) Ultrasonic probes for medical imaging, diagnosing and treatments; (ii) Electromechanical transducers for undersea communications (SONAR); (iii) Non-volatile ferroelectric random access memories (FeRAM), etc.